1.

The % by volume of `C_(4)H_(10)` in a gaseous mixture of `C_(4)H_(10), CH_(4)` and `CO_(2)` is 40. When 200 ml of this mixture is burnt completely in excess of `O_(2)` and then pass through aq. KOH then volume contraction will be -A. 220 mlB. 340 mlC. 440 mlD. 560 ml

Answer» Correct Answer - C
`ubrace(C_(4)H_(10), CH_(4),CO_(2))_("200 mL")`
`C_(4)H_(10) = 0.4 xx 200 = 80 ml`
`CH_(4) = x ml`
`CO_(2) = (120 - x) ml`
`C_(4)H_(10) + (13)/(2) O_(2) rarr 4CO_(2) + 5H_(2)O`
`{:(80 ml,," 320 ml",),(CH_(4) + 2O_(2),rarr,CO_(2) + 2H_(2)O,),(x ml,,x ml,):}`
Total `CO_(2) = 320 + x + 120 - x`
`= 440 ml`


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