1.

The charge/size ratio of a cation determines its polarizing power. Which one of the following sequences represents the increasing order of the polarizing power of the cationic species, K^(+), Ca^(2+), Mg^(2+), Be^(2+)?

Answer»

`CA^(2+) lt Mg^(2+ ) lt Be^(2+ ) lt K^(+)`
`Mg^(2+ ) lt Be^(2+) lt K^(+) lt Ca^(2+)`
`Be^(2+ ) lt K^(+) lt Ca^(2+) lt Mg^(2+)`
`K^(+) ltCa^(2+) ltMg^(2+) ltBe^(2+)`

SOLUTION :`K^(+) ltCa^(2+) ltMg^(2+) ltBe^(2+)`
HIGH charge and small size of the CATIONS increases pol.arisation.
As the size of the given cations decreases as
`K^(+) gt Ca^(2+) gt Mg^(2+) gt Be^(2+)`
Hence, polarising power decreases as
`K^(+) ltCa^(2+) ltMg^(2+) ltBe^(2+)`


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