1.

The combustion of benzene (l) gives CO_(2)(g) and H_(2)O(l).Given that heat of combustion of benzene at constant volume is -3263.9 kJ mol^(-1) at 25^(@)C, heat of combustion (in kJ mol^(-1)) of benzene at constant pressure will be (R = 8.314 JK^(-1) mol^(-1)).

Answer»

4152.6
`-452.46`
3260
`-3267.6`

SOLUTION :`C_(6)H_(6)(l) + (15)/(2) O_(2)(g) to 6CO_(2)(g) + 3H_(2)O(l)`
`Deltan_(g) = 6-15/2 = -3/2`
`DeltaH =DeltaU - Deltan_(g)RT`
`= -3263.9 + (-3/2) xx 8.314 xx 10^(-3) xx 298`
` = -3263.9 - 3.716`
` = - 3267.678`.


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