1.

The compound 'A' is a colourless solid. It gives following tests: Test-I: The addition of compound 'A' solution to a solution of KI, followed by acidification with dilute H_(2)SO_(4), results in the formation of brown coloured compound 'B'. Test-II: The acidified KMnO_(4) solution is decolourized, by a solution of compound 'A', but no gas is evolved. Which of the following reaction(s) is/are correctly matched about Test-I and Test-II?

Answer»

`2NaNO_(2)+3KI +2H_(2)SO_(4) rarr KI_(3) +2NO +2H_(2)O +2SO_(4)^(2-)+2K^(+) +2Na^(+)`
`5NaNO_(2) +2KMnO_(4)+3H_(2)SO_(4) rarr 5NaNO_(3)+2MnSO_(4)+K_(2)SO_(4)+3H_(2)O`
Test-(I) and Test-(II) both are redox reactions
Test-(I) and Test-(II) both are PRECIPITATION reactions

Answer :A::B::C


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