InterviewSolution
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InterviewSolution
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The compound X `(C_(4)H_(11)N)` on treatement with nitrous acid gives a tertiary alcohol `(C_(4)H_(10)O)`. The compound X must also respond toA. Mustard oil reactionB. Libermann nitroso reactionC. Beckmann rearrangementD. Carbylamine reaction. |
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Answer» Correct Answer - A::D X must be `1^(@)` amine as it produces alcohol by reaction with `HNO_(2)`. The probable structure of X is tertiary butyl amine `{:(" "CH_(3)" "CH_(3)),(" |"" |"),(CH_(3)-C-NH_(2) overset(HNO_(2))(rarr) CH_(3)-C-OH),(" |"" |"),(" "CH_(3)" "CH_(3)),(" "(X) 1^(@)" Amine "3^(@)" Alcohol"):}` X being `1^(@)` amine should also respond to mustard oil reaction and carbyl amine reaction. |
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