1.

The concept of oxidation number (O.N) is very important in under standing redox reaction s it helps to identify the oxidant / reductant in a redox reaction it also helps to (i) find oiut thepossible molecular formula of any neutral compound and (ii) to balance redox reaction when copper is treated with a certain concentraton of nitric acid oxide and nitrogen dioxide are liberated in equal volume according to the equation XCu+YHNO_(3)rarrCu(NO_(3))_(2)+NO+NO_(2)+H_(2)O the coefficeents of x and y are

Answer»

2 and 3
2 and 6
1 and 3
3 and 8

Solution :Balanced equation for evolution of NO and `NO_(2)` respectively are
`3Cu +8HNO_(3) rarr 3Cu(NO_(3))_(2)+2NO+4H_(2)O`
`Cu+4HNO_(3)rarrCu(NO_(3))_(2)+2NO_(2)+2H_(2)O`
adding eqt (i) and (II) we have
`4Cu+12 HNO_(3)rarr2Cu(NO_(3))_(2)+NO_(2)+NO+3H_(2)O`
Thus coefficient x ANDY of Cu and `HNO_(3)` respecitively are 2and 6


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