1.

The correct of increasing bond angles in the following species is

Answer»

`CIO_(2)^(-) lt Cl_(2)O lt ClO_(2)`
`Cl_(2)O lt ClO_(2) lt ClO_(2)^(-)`
`ClO_(2) lt Cl_(2)O lt ClO_(2)^(-)`
`Cl_(2)O lt ClO_(2)^(-) lt ClO_(2)`

Solution :
In `ClO_(2), Cl is sp^(2)` -hybridized and the bond ANGLE
is `180^(@)` . In `Cl_(2)O,OIS sp^(3)` -hybridized . HOWEVER ,
dueto repulsions between two BIG sized Cl atoms,
the bond angle increases from `109.5^(@)` to `111^(@)` . In
`ClO_(2)^(-) ,Cl` ATOM is `sp^(3)`-hybridizedbut due to
lp-bp repulsions, the angle decreases from `109.5^(@)`
to `103^(@)` .Thus, the increasing order of bond angles
is `ClO_(2)^(-) lt Cl_(2)O lt ClO_(2)`.


Discussion

No Comment Found