1.

The cryoscopic constant and freezing point of benzene is "5.12 K kg mol"^(-1) and 278.6 K respectively. At what temperature will one molal solution of benzene containing a nonelectrolyte (i=1) freeze?

Answer»

SOLUTION :Depression in breezing point `(DeltaT_(f))` for dilute solution is directly proportional to molality
`DeltaT_(f)alpham`
`DeltaT_(f)=K_(f)m`
`"GIVEN : "K_(f)="5.12 K kg MOL"^(-1)`
`T_(f)^(@)=278.6K`
`m="1 MOLAL"DeltaT_(f)=5.12 xx1`
`""DeltaT_(f)=5.12K`
`W.K.T""Delta_(f)=T_(f)^(@)-T_(f)`
`5.12 =278.6-T_(f)`
`T_(f)=278.6-5.12`
`T_(f)=273.48K`


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