1.

The decomposition of NH₃ on platinum surface is zero order reaction. What are the rates of production of N₂ and H₂ respectively if k = 2.5 × 10⁻⁴ mol⁻¹ L s⁻¹? *(a) 2.5 × 10⁻⁴ molL⁻¹ s⁻¹and 7.5 × 10⁻⁴ molL⁻¹ s⁻¹(b) 5.5 × 10⁻⁴ molL⁻¹ s⁻¹and 7.5 × 10⁻⁴ molL⁻¹ s⁻¹(c) 7.5 × 10⁻⁴ molL⁻¹ s⁻¹and 2.5 × 10⁻⁴ molL⁻¹ s⁻¹(d) 8.5 × 10⁻⁴ molL⁻¹ s⁻¹and 7.5 × 10⁻⁴ molL⁻¹ s⁻¹​

Answer»

2NH  3Pt  N 2  +3H  2

​ Rate=−  

21[  dtd[NH  3   ]  ]=[  dtd[N  2  ]  ]=+  31  [ dtd[H  2  ]  ]

As the order of the reaction is zero HENCE rate of reaction  

Rate of reaction = k

Rate of production of N  2= 2.5×10  −4molL  −1  s  −1

 

Rate of production OFH  2  =3×2.5×10  −4

=7.5×10  −4  molL  −1  s  −1

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