1.

The decreasing order of stability of the carbonium ions C_(6)H_(5)CH_(2)^(+) (I), p-(CH_(3)O)C_(6)H_(4)CH_(2)^(+) (II), p-(NO_(2))C_(6)H_(4)CH_(2)^(+) (III), p-(CH_(3))C_(6)H_(4)CH_(2)^(+) (IV) is

Answer»

`IV gt II gt I gt III`
`II gt IV gt III gt I`
`II gt IV gt I gt III`
`IV gt II gt III gt I`

SOLUTION :Electron-donating groups `(OCH_(3) gt CH_(3))` increases while electron-withdrawing groups `(NO_(2))` decreases the stability of substituted carbonium IONS. Thus,option (C) is correct.


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