InterviewSolution
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InterviewSolution
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The `E^(@)` values for the changes given below are measured againest `NHE` at `27^(@)C`. `Cu^(2+) + e rarr Cu^(+), E^(@) = + 0.15 V`, `Cu^(+) + e rarr Cu, E^(@) = + 0.50 V`, `Zn^(2+) + 2e rarr Zn, E^(@) = - 0.76 V` The temperature coefficient of emf a cell designed as `Zn"|"underset(1 M)(Zn^(2+))"||"underset(0.1 M)(Cu^(2+))"|"Cu` is `-1.4 xx 10^(-4)V` per degree. For a cell reaction in equilibrium `DeltaG = 0` and `DeltaG^(@) = -2.303 RTlog_(10)K_(c)`. The heat of reaction and entropy change during the reaction are are related by `DeltaG = DeltaH - TDeltaS`. The `E^(@)` of `Zn|Zn^(2+)||Cu^(2+)|Cu` cell is :A. `1.076 V`B. `1.091 V`C. `1.117 V`D. `0.90 V` |
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Answer» Correct Answer - A `E_(cell) = 1.085 + (0.059)/(2)"log"(0.1)/(0.2) = (0.1)/(0.2) = 1.076` |
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