1.

The function of boiling the sodium extract with conc. HNO_(3) before testing for halogen as:

Answer»

to make the solution acidic
to make the solution clear
to CONVERT `Fe^(2+)` to `Fe^(3+)`
to destroy `CN^(-)` and `S^(2-)` ions

Solution :If N and S are ALREADY present, they will hinder in test of halogens as `NaCN` and `Na_(2)S` will GIVE white or black precipitate with `AgNO_(3)`. Boiling conc. `HNO_(3)` is thus used to remove `CN^(-)` and `S^(2-)` ions in the FORM of volatile HCN and `H_(2)S`.


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