1.

The heat liberated when 1.89 g of benzoic acid is burnt in abomb calorimeterat25^(@)Cincreases the temperature of18.94kgof water by 0.632^(@)C. If the specific heat of water at25^(@)C is 0.998cal// g// deg, the value of heat of combustion of benzoic acid is

Answer»

`881.1kcal`
`771.4 KCAL`
`981.1kcal`
`871.2kcal`

Solution :Heat absorbed by water `= m xx s xx DELTAT`
`= 18940 g xx 0.998 cal^(-1) g deg^(-1) xx 0.632 ^(@) C`
`=11946.14 cal`
`:. ` Heat produced on combustion of1.89g of benzoic ACID`= 11946.14cal`
Molar mass of benzoic acid `( C_(6)H_(5) COOH) = 122g`
`:. `Molar heat of combustion
`= ( 11946.14)/( 1.89) xx 12 cal`
`=771126.5 cal = 771.12 kcal`.


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