1.

The heat of combustion of C_(2)H_(6) is -368.4 kcal. Calculate the heat of combustion of C_(2)H_(2), when the heat of combustion of H_(2) is 68.32 kcal mol^(-1). C_(2)H_(4)(g) + H_(2)(g) rarr C_(2)H_(6)(g) , Delta H = 37.1 kcal.

Answer»

Solution :`C_(2)H_(4)(G) + H_(2)(g) RARR C_(2)H_(6)(g) , Delta H = -37.1 kcl`
`Delta H_(c )C_(2)H_(6) = -368.4 kcal, Delta H_(c )C_(2)H_(4) = ? , Delta H_(c )H_(2(g)) = -68.32 kcal`
`Delta H = SigmaDelta H_("c(reactants)") = -Sigma Delta H_("c(products)")`
`Delta H = Delta H_(c )C_(2)H_(4) + Delta H_(c )H_(2(g)) - Delta H_(c )C_(2)H_(6(c ))`
`-37.1 kcal = Delta H_(c )C_(2)H_(4) - 68.32 - (-368.4)`
`Delta H_(c )C_(2)H_(4) = -337.18 K cal`.


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