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The heat of combustion of ethene gas is 330 Kcal "mol"^(-1) calculate gtc=clt bond energy (in kcal/mol) assuming that bond energy of C-H bond is 93.6 Kcal "mol"^(-1) Given :DeltaH_f^@ for CO_2(g) and H_2O(l) are -94.2 and -61 Kcal "mol"^(-1) respectively.Heat of atomisation of carbon and hydrogen are 150 and 51.5 Kcal "mol"^(-1) respectively. |
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Answer» `:.-330=[2XX(94.2)+2(-61)]-[DeltaH_f^@C_2H_4]:.DeltaH_f^@(C_2H_4)=19.6 Kcal mol^(-1)` `:. 2C(s)+2H_2(g)toCH_2=CH_2(g),DeltaH_f=19.6` `because DeltaH_("Reaction")=2DeltaH_("ATM" ( C))+4DeltaH_("atm"(H))-4B.E._((C=C))` 19.6=2x150+4x51.5-4x93.6-`B.E._((C=C))` `B.E._((C=C))=112` Kcal/mol |
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