1.

The heat of reaction for an endothermic reaction at constant volume in equilibrium is 1200 cal more than al constant pressure at 300K, then

Answer»

<P>`Deltan_((g))= -2`
`(K_(P))/(K_(c))=1.648 XX 10^(-3)`
`Deltan_((g))= +2`
`(K_(c))/(K_(P))=1.648 xx 10^(-3)`

Solution :`DeltaU=DeltaH+1200`
`DeltaU-DeltaH=1200=Delta n_((g))RT`
`Delta n_((g))=(-1200)/(2 xx 300)= -2 implies (Kp)/(Kc)=(RT)^(-2)=(0.0821 xx 300)^(-2)=1.648 xx 10^(-3)`


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