1.

The increasing order of first ionization enthalpies of the elements B, P, S and F (lowest first) is .........

Answer»

`P lt S lt B lt F`
`F lt S lt P lt B`
`B lt S lt P lt F`
`B lt P lt S lt F`

SOLUTION :"Generally in a period as atomic number is higher its first IONISATION enthalpy is greater",
ACCORDINGLY first ionisation enthalpy of `B lt F`
(both of second period) and of `P lt S` (both of third period)
The `I^(ST)` ionisation enthalpy decreases from top to botton in a GROUP .
` :. I^(st)`ionisation potential order should be: `B lt F " and " P lt S`
`P [Ne] 3s^(2) 3px^(1) 3py^(1) 3p_(2)^(1)`
and `S [Ne] 3s^(2) 3px^(2) 3py^(1) 3p_(z)^(1)`
P has stable half filled (p)
Electronic configuration, hence`Delta_(i)H(P) gt Delta_(i)H(S)`
` :. ` The correct order is `B lt F " and " S lt P `
F is of smallest size among these all.
`:. F`has highest `Delta_(i)H`
` :. `Orderis `B lt S lt P lt F`


Discussion

No Comment Found