1.

The intermolecular forces of attraction (i.e., H-bonding and van der waal's forces) exist among polar and non-polar species which effect melting point, boiling point, solubility and viscosity of covalent compounds : Q. Select the incorrect order of boiling point between the following compounds:

Answer»

`N_(2)HltCH_(3)N_(3)`
`Me_(2)SO_(4)ltH_(2)SO_(4)`
`Me_(3)BO_(3)ltB(OH)_(3)`
`BF_(3)ltBI_(2)`

Solution :`to` Boiling point of `HN_(3)gtCH_(3)N_(3)` as in hydrazoic acid `(HN_(3))` intermolecular H-bonding occurs and its BOND ENERGY is higher than weak dipole-dipole interactions present in`CH_(3)N_(3)`
`to`Boiling point of `BI_(3)` is greater than that of`BF_(3)` as molecular weight of `BI_(3)` is higherhtan that of `BF_(3)` .
`to`Due to intermolecular H-bonding in `H_(2)SO_(4)` its boiling point is higher than `Me_(2)SO_(4)`.
`to` Similarly due to intermolecular H-bonding in `B(OH)_(3)` its boiling point than that of`Me_(2)BO_(3)`.


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