1.

The ioisation constant of a weak electroluytes is `25 xx 10^(-6)` and the equivalent conductance of its ` 0.01M` solution is `19.6 S cm^2 eq^(-1)`. The equivalent conductance at infinited dilution of the electrolyte is ` S cm^2 sq^(-1)`. is .A. ` 50`B. ` 196`C. `392`D. ` 384`

Answer» Correct Answer - C
`{:(HA,hArr,H^(+),+,A^(-)),(C,,0,,0),(C-Calpha,,Calpha,,Calpha):}`
Or `K= C alpha^2`
Or `25 xx 10^(-6) = 10^(-2) . alpha^2`
Or `alpha = 5 xx 10^(-2)`
also `alpha= (lambda_v)/(lambda_("infty")) = (19.6)/(lambda_("infty")) = (19.6)/(5 xx10^(-2)) = 392`.


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