1.

The mass of carbon anode consumed (givingonly carbon dioxide) in the production of 270 kgof aluminium metal from bauxite by the Hallprocess is (Atmic mass of Al 27)22.Hint : 2Al,0, +3C 4Al+3co2 ][AIPMT 2005](A) 180 kg(C) 540 kg(B) 270 kg(D) 90 kg

Answer»

Bauxite is not directly used in Hall's process. It is first converted into alumina by Bayer's process.Reaction of carbon withAl2O3forming Aluminium and carbon dioxideis given :2Al2O3+ 3C→4Al + 3CO2

​Molar mass of Al = 27 gmol-1​​Molar mass of Al2O3= 118 g mol-1​Molar mass of Carbon = 12 g mol-1

Thus, we can see that according to this reaction, (4×27) = 108 g of Al is formed from the reduction of Al2O3by (3×12) = 36 g of carbon.108 g of Al produced by 36 g of Carbon27000 g of Al is formed by (36 / 108)×27000=90000 g or 90 kg (aaprox.)



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