1.

The maximum pH of a solution which is 0.10 M in Mg ^(2+ )from which Mg (OH) _ 2 is not precipitated is : ( Given K_(sp) " of " Mg (OH)_2 =1.2 xx 10^(-11) M)

Answer»

`4. 96`
`6.96`
`7. 54 `
` 9. 04`

Solution :` Ag_2Cr O_4 HARR 2Ag^(+)+CrO_4^(-2) `
` "" 2S "" S `
` (i)0.1 M Ag^(+)" IONS is common ION "`
` 9 xx 10 ^(-12) = ( 2S)^(2)(0.1 )^(2)xx S RARR S =9 xx 10 ^(-10 )M`
` (ii)0.1 M CrO_4^(-2)" ions is commonion " `
` 9xx 10 ^(_12)=( 2S)^(2)(0.1)rArr 9 xx 10 ^(_12)= 4S^(2)0.1 `
` S = sqrt( (9)/(4) xx 10 ^(-11))~~4.5 xx 10^(_6)M`
`[Mg^(+2) ][OH^(-)] ltKsp , (0.1)[OH^(-) ]^(2)lt 1.2 xx 10 ^(-11)`
` [OH^(-)] lt sqrt(1.2 xx 10 ^(-10)), [OH^(-) ] lt 1.09xx 10 ^(-5)POH = 4. 96 , PH = 9. 04`


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