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The measure of net molecular polarity is a quantity called dipole moment which is defined as the magnitude of the charge Q at either end of the molecular dipole times the distance 'r' between the charge : mu=Qxxr Molecular polarities give rise to some of the forces that occur between molecules.Such forces are termed as intermolecular forces.These molecular forces are of several different types including dipole-dipole forces, London dispersion forces, hydrogen bonds and ion-dipole forces (operate between ions and molecules).These intermolecular forces are electrical in origin and results from the mutual attraction of unlike charges or the mutual repulsion of like charges. A formal positive charge on the central atom affect the size of orbitals.A formal positive charge on central atom will pull in all electrons towards the nucleus and this will leads to the contraction in size of orbitals. Select the correct statement. |
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Answer» In trisilyl amine , all N-Si bond lengths are bigger than that of normal N-Si single covalent bond (B)`PH_5` can not undergo `sp^3d` hybridisation as there is muchlarge difference in size of s, p and d orbitals `PH_5` does not exist as no partial POSITIVE charge DEVELOPS on P atom. (C )Dipole moment of `CH_2Cl` is greater than `CH_3F` due to greater charge sepration on carbon and chlorine atoms in `CH_3Cl`. (D) It is correct order. The strength of hydrogen bond depends upon : (i)size (ii)electronegativity and (iii) ease of donation of electron pair by electronegative element. Higher the value of electronegativity and smaller the size of covalently BONDED atom to H atom stronger is the hydrogen bonding. |
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