1.

The mechanism of the reaction of propene with HOCI (Cl_2 + H_2O)will proceed through which of the following intermediates?

Answer»

`CH_3 - overset(oplus)(CH)-CH_2OH`
`CH-3-overset(oplus)(CH)-CH_2Cl`
`CH_3-overset(OH)(CH)-overset(oplus)(C)H_3`
`CH_3-overset(Cl)(CH)-overset(oplus)(C)H_2`

SOLUTION :The CHLORINE atom has the LESSER electronegativity and is the electrophile and the carbocation in this intermediate has the GREATER number of hyperconjugation resonance forms.


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