1.

The Mn^(3+) ion is unstable in solution and undergoes disproportionation to give Mn^(2+),MnO_(2),andH^(+) ion. Write a balanced ionic equation for the reaction.

Answer»

SOLUTION :`Mn_((aq))^(+3)toMn_((aq))^(+2)+MnO_(2(s))+H_((aq))^(+)`
HALF reaction …
O.H.R. : `Mn_((aq))^(+3)toMnO_(2(s))`
R.H.R. : `Mn_((aq))^(+3)toMn_((aq))^(+2)`
Balancing the reaction on adding `e^(-)`
O.H.R. : `Mn_((aq))^(+3)toMnO_(2(s))+e^(-)`
R.H.R. : `Mn_((aq))^(+3)+e^(-)toMn_((aq))^(+2)`
ADDITION of `H_(2)O` for the balancing of hydrogen and OXYGEN.
O.H.R. : `Mn_((aq))^(+3)+2H_(2)OtoMnO_(2(s))+4H_((aq))^(+)+e^(-)`
R.H.R. : `Mn_((aq))^(+3)+e^(-)toMn_((aq))^(+2)`
Now on addition of O.H.R. and R.H.R.
`2Mn_((aq))^(+3)+2H_(2)O_((L))toMnO_(2(s))+2Mn_((aq))^(+2)+4H_((aq))^(+)`


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