1.

The molar entropies of HI_((g)), H_((g)) and I_((g)) at 298K are 206.5, 114.6, and 180.7 J mol^(-1)K^(-1) respectively. Using the DeltaG^(@) given below, calculate the bond energy of HI. HI_((g)) rarr H_((g)) + I_((g)), DeltaG^(@) = 271.8kJ (Give your answer after divide with 49.7)

Answer»

282.4
298.3
290.1
315.4

Solution :`HI RARR H + I`
`Delta S^(0) = S_(P) - S_(R ) = (114.6 + 180.7) - (206.5) = 88.8`
`Delta G^(0) = Delta H^(0) - T Delta S^(0) = 271.8`
`rArr Delta H^(0) = 271.8 + (298)/(1000) xx (88.8) = 298.3`


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