1.

The mole fraction of water in a solution of HCI is 0.78. Calculate the molality of the solution.

Answer»

SOLUTION :Mole fraction of WATER = 0.78
Mole fraction of HCI = `1 - 0.78 = 0.22`. SUPPOSE, the solution contains `n_(1)`moles of HCI and `n_2` moles of water. Therefore,
`n_(1)/(n_(1) + n_(2)) = 0.22`……..(i)
and `n_(2)/(n_(1) + n_(2)) = 0.78`……...........(ii)
DIVIDING eq. (i) by eq. (ii), we have
`n_(1)/n_(2) = 0.22/0.78 = 0.28`.............(iii)
Since, molality refers to the number of moles of solute dissolved in 1000 g of solvent (water in the present case),
`n_(2) = 1000/18 = 55.55`
Substituting the value in eq. (iii), we have
`n_(1)/55.55 =0.28`
or `n_(1) = 0.28 xx 55.55 = 15.55`
Hence, the molality of the given solution is 15.55 m.


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