1.

The molecular mass of an organic acid was determind by the study of its barium salt. `4.290 g` of salt was converted to free acid by the reaction with `21.64 mL` of water of hydration per `Ba^(2+)` ion and the acid is monobasic. What is molecular weight of anhydrous acidgt

Answer» mEq of Braium salt = mEq of acid
`(4.290)/(Mw..2) xx 1000 = 21.64 xx 0.477 xx 2`
Molecular weight of salf = 415.60
Molecular weight of anion
`= (("Mw of salt" - Mw of Ba^(2+) - Mw of 2 H_(2) O))/(2)`
`= (415.60 - 137 - 36)/(2) = 121.16`
`:.` Molecular weight of acid `= 121.6 + 1 = 122.6`


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