1.

The molecule having smallest bond angle is

Answer»

`AsCl_(3)`
`SbCl_(3)`
`PCl_(3)`
`NCl_(3)`

SOLUTION :`SbCl_(3)`
As we move down the group the size of atom increases and as size of central atom increases, lone pair-bond pair repulsion also increases. Thus bond angle decreases.
Increasing order of ATOMIC radius :
`N lt P lt As lt Sb `
Decreasing order of bond angle :
`NCl_(3) GT PCl_(3) gt AsCl_(3) gt SbCl_(3)`


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