1.

The number of structural and configurational isomers of a bromo compound, C_(5)H_(9)Br, formed by the additionn of HBr to 2-penthyne respectively are

Answer»

1 and 2
2 and 4
4 and 2
2 and 1

Solution :ADDITION of HBr to 2-pentyne gives two STRUCTURAL isomers (I) and (II).
`CH_(3)-C-=C-CH_(2)CH_(3) OVERSET(HBr) underset((I))(CH_(3)C(Br)=CHCH_(2)CH_(3))+underset((II))(CH_(3)CH=C(Br)CH_(2)CH_(3))`
Each one of these will EXIST as a PAIR of geometrical isomers as shown below:

thus, there are two structural and four configurational isomers.


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