1.

The percentage of pyridine (C_(5)H_(5)O) that forms pyridinium ion (C_(5)H_(5) overset(+)NH)in a 0.10 M aqueons pyridine solution is (K_(b) for C_(5)H_(5)N=1.7 xx 10^(-9))

Answer»

0.0077
0.016
6.0E-5
0.00013

Solution :Pyridine is a weak base. In AQUEOUS solution, it ionizes as
`{:(,C_(5)H_(5)N+H_(2)O hArr C_(5)H_(5)overset(+)NH+OH^(-)),("Initial conc."," "c "" 0 ""0),("At. eqm." ,C(1-alpha)"" calpha ""calpha),(,K_(b) ~=C alpha^(2) ""("By Ostwald's DILUTION law")):}`
`alpha = SQRT((K_(b))/(C))=sqrt((1.7xx10^(-9))/(01))=sqrt(1.7xx10^(-8))=13.10^(-4)`
`: .` % disssociation (i.e. , % that forms `C_(5)H_(5)overset(+)NH` ion) `=1.3xx10^(-4)xx100=0.013 %`


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