1.

The pH of a solution containing 0.20M CH_(3)COOH and 0.30M CH_(3)COONa is

Answer»

`2.89`
`4.92`
`5.04`
`3.89`

Solution :SINCE we are dealing with a mixture of a weak ACID and its salt with a strong base, we can calculate the pH of the solution by using the Henderson-Hasselbalch EQUATION:
`pH=pK_(a)+"log"(C_("salt"))/(C_("acid"))`
In this CASE, we need to calculate `pK_(a)` and the acid FIRST:
`pK_(a)= -logK_(a)`
`= -log(1.8xx10^(-5))`
`=4.74`
Now, we substitute the value of `pK_(a)` and concentrations of the acid and its salt:
`pH=pK_(a)+"log"(C_("salt"))/(C_("acid"))`
`=4.74+"log"(0.30)/(0.20)`
`=4.74+log(1.5)`
`=4.92`


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