1.

The pH of neutral water at 25^@C is 7.0. As the temperature increases, ionisation of water increases, however, the concentration of H ions and OH^-ions are equal. What will be the pH of pure water at 60^@C ?

Answer»

Equal to 7.0
Greater than 7.0
Less than 7.0
Equal to zero

Solution :The PH of neutral WATER at `25^@C` is 7.0.
As `25^@C[H^+]=[OH^-]=10^(-7)`
`K_w=[H^+][OH^-]=10^(-14)`
On heating , `K_w` increases, i.e.,
`[H^+][OH^-] gt 10^(-14)`
As `[H^+]=[OH^-]` or , `[H^+]^2 gt = 10^(-14)`
or `[H^+] gt 10^(-7)` M
`therefore pH lt 7`
With rise in temperature, pH of pure water decreases and it become less than 7 at `60^@`C.


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