1.

The pH of the solution formed on mixing 20 mL of0.05 MH_(2)SO_(4) with 5.0 mL of 0.45 M NaOH of 298 K is

Answer»

6
2
12
7

SOLUTION :`2 NAOH+H_(2)SO_(4)rarrNa_(2)SO_(4)+2H_(2)O`
20 mLof 0.05 M `H_(2)SO_(4)=20xx0.05` millimoles
= 1 millimole
5 mL of 0.45 M NaOH `= 5 xx 0.45` millimoles
`=2.25` millimole
2 millimoles of NaOH REACT with 1 millimole of `H_(2)SO_(4)`
`:.` NaOH left in the solution = 0.5 millimole Volume of solution = 25 mL
`:. [OH^(-)]= (0.5)/(25)M = 0.01 M = 10^(-2)M`
`:. [H^(+)]=10^(-12) ` or pH = 12


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