1.

The pK_a of acetic acid and pK_b of ammonium hydroxide are 4.76 and 4.75 respectively . Calculate the pH of ammonium acetate solution.

Answer»

Solution :`pK_a` of `(CH_3COOH)`= 4.76
`pK_b` of `(NH_4OH)`= 4.75
Ammonium ACETATE is a SALT of this both.
The PH of ammonium acetate solution is calculate by FOLLOWING EQUATION.
`pH=7+1/2(pK_a + pK_b)`
`=7+1/2(4.76-4.75)`
`=7+1/2(0.01)=7+0.005 = 7.005`


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