1.

The polymerisation of propene to linear polypropene is represented by the reaction:where n has a large integral value. The average enthalpies of bond dissociation for (C=C) and (C−C) at 298 K are +590 and +331 kJmol−1, respectively. The enthalpy of polymerisation is−360 kJmol−1. Find the value of n.

Answer» The polymerisation of propene to linear polypropene is represented by the reaction:

where n has a large integral value. The average enthalpies of bond dissociation for (C=C) and (CC) at 298 K are +590 and +331 kJmol1, respectively. The enthalpy of polymerisation is

360 kJmol1. Find the value of n.


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