1.

The pyknometer density of NaCl crystal is 2.165xx10^(3)kg m^(-3) while its X - rays density is 2.178xx10^(3)kg m^(-3). The fraction of the unoccupied sites in NaCl crystal is

Answer»

`5.968`
`5.96xx10^(-2)`
`5.96xx10^(-3)`
`5.96xx10^(-4)`

SOLUTION :Molar volume from pyknometer density `= (M)/(2.165xx10^(3))m^(3)`
Molar volume from X - RAY density `= (M)/(2.178xx10^(3))m^(3)`
`therefore` Volume unoccupied `=((1)/(2.165)-(1)/(2.178))(M)/(10^(3))m^(3)`
Fraction unoccupied `=((1)/(2.165)-(1)/(2.178))//(1)/(2.165)`
`= 5.96xx10^(-3)`


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