1.

The pyknometric density of sodium chloride crystals is2.165 xx 10^(3) kg m^(-3)while X -ray density is2.178 xx 10^(3)kg m^(-3) . Thefraction of the unoccupied sites in sodium chloride crystal is

Answer»

5.96
`5.96 xx 10^(-2)`
`5.96 xx 10^(-1)`
` 5.96 xx 10^(-3)`

Solution :MOLAR VOLUME from pyknometric density
` = M/(2.165 xx 10^(3)) m^(3)`
Molar volume from X-ray density
` M/(2.178 xx 10^(3)) m^(3)`
Volume unoccpied
`M/10^(3) ( 1/(2.165) - 1/(2.178))m^(3) = (( 0.013 M xx10^(-3))/(2.165 xx 2.178))//((M xx 10^(-3))/2.165) = 5.96 xx 10^(-3)`


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