1.

The radical halogenation of 2-methylpropane gives two products: (CH_(3))_(2)CHCH_(2)X (minor) and (CH_(3))_(3)CX (major) Chlorination gives a larger amount of the minor product than does bromination, why?

Answer»

Bromine is more reactive than chlorine and is able to ATTACK the LESS reactive `3^(@)C-H`
Bromine atoms are less reactive (more selective) than chlorine, and PREFERENTIALLY attack the weaker `3^(@)C-H` bond
The methyl groups are more hindered to attack by the LARGER bromine atom.
Bromination is reversible and more STABLE `3^(@)-` alkyl bromide is formed exlusively.

Answer :B


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