1.

The rapid change of pH near the stoichiometric point of an acid-base titration is the basis of indicator detection. pH of the solution is related to ratio of concentration of conjugate acid. (HNn) and the base [In^(-)) forms of the indicator by the expression

Answer»

`LOG.([In^(-)])/([In^(-)])= pK_(In) -PH`
`log.([HIN^(-)])/([In^(-)])= pK_(In) -pH`
`log.([HIn^(-)])/([In^(-)])= pH_(In) -pK_(In)`
`log.([In^(-)])/([ H In^(-)])= pH_(In) -pK_(In)`

Solution :`pH = pK_(a)+log. (["Conjugate base"])/(["ACID"])`
`:. pH - pK_(In)=log. ([In^(-)])/([HIn])`


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