1.

The rate of a gaseous reaction is halved when the volume of the vessel is doubled. What is the order of reaction ?

Answer»

SOLUTION :Suppose, order of reaction is n and the reaction is A (G) `to`Products
RATE=`k[A]^n`…(i)
When volume is doubled, molar conc. becomes half and rate of reaction gets halved.
`"Rate"/2=k(A/2)^n`…(ii)
DIVIDING equation (i) by equation (ii),
`(2)^1 =(2)^n`
n=1


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