1.

The reaction which is in dynamic equilibrium, ensured us, that the reaction is reversible . But if that the reaction is in equilibrium. The reaction quotient predict either the reversiblereaction is in equilibrium or tries to achieve equilibrium. In those reactions which have not achieved equilibrium, we obtain reaction quotient Q_(c) in place of equilibrium constant (K_(c)) by substituting the concentration of reactant and product at the time, at whih we have to calculate the value of Q_(c) . To determine the direction at which the net reaction will proceed to achieve equilibrium, we compare values of Q_(c) and K_(c). The three possible cases are shown as comparison of K_(c) and Q_(c) in the following figures. Change in Gibbs free energy, i.e., Delta G is the driving force of any reaction. For spontaneous reaction , Delta G =-ve For non-spontaneous reaction , Delta G=+ve For reaction at equilibrium , Delta G =0 Thermodynamically, we know that Delta G= Delta G^(@)+ RTln Q, where Q is reaction quotient and Delta G^(@)= change in Gibbs energy at standard condition. For equilibrium A(g) hArr B(g) (K_(eq) =1.732) If the pressure of the system [varied by introducing a stream of A (g) and B (g) is representedby the curve at constant temperature T. For the equilibrium n Butane (g) hArrIsobutane (g),(K_(eq)=1.732)If the pressure of the system (varied by introducing a stream of n butane and isobutane ) is represented by the curve at constanttemperature T. At a particular point Q, which of the following statements holds good ?

Answer»

The REACTION moves in the backward direction.
The reaction movess in the FORWARD direction.
The reaction is at EQUILIBRIUM .
The data is insufficient to prodict

Answer :C


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