1.

The reagent (s) that can selectively precipitate S^(2-) from a mixture of S^(2-) and SO_(4)^(2-) in aqueous solution is (are)

Answer»

`CuCl_(2)`
`BaCl_(2)`
`Pb (OOC CH_(3))_(2)`
`Na_(2) [Fe(CN)_(5) NO]`

Solution :`CuCl_(2)` gives a black precipitate with `S^(2-)` ions.
`Cu^(2+) + S^(2-) rarr underset(("Black ppt."))(CuS)`
`CuSO_(4)` formed remains soluble in AQUEOUS solution


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