1.

The relation between internal energy U, pressure P and volume V of a gas in an adiabatic process is U = a + bPV where a and b are positive constants. What is the value of gamma ?

Answer»

`(a)/(b)`
`(b+1)/(b)`
`(a+1)/(a)`
`(b)/(a)`

SOLUTION :For an ADIABATIC process, dQ = 0
From the first law of THERMODYNAMICS, we get
or `bPdV + bVdP + PdV = 0` or (b+1)PdV + bVdP = 0
or `(b+1) (DV)/(V) + b(dP)/(P) = 0`
or `(b+1)(dV)/(V) = -b(dP)/(P)`
Integrating both sides, we get (b+1) ln V + b ln P = constant or ln `(V^(b+1)P^(b))` = constant or `PV^((b+1)/(b))` = another constant
Compare with the STANDARD equation of an adiabatic process `PV^(gamma)` = constant, we get `gamma = (b+1)/(b)`


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