1.

The relative order of esterification of the following alcohols is

Answer»

`I lt II lt III`
`I gt II gt III`
`I lt III lt II`
`I gt III gt II`

SOLUTION :The rate DETERMINING step for esterification is the addition of ALCOHOL. The rate determining step involves change of HYBRIDISATION of carbonyl carbon from `sp^(2)` to `sp^(3)`, and consequently steric retardation increases as the size of alcohol increases and hence the rate of esterification DECREASES


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