The root mean square speed of an ideal gas is given by : u_("rms") = sqrt((3RT)/M)Thus we conclude that u_("rms")speed of the ideal gas molecules is proportional to square root of the temperature and inversely proportional to the square root of the molar mass. The translational kinetic energy per mole can also be given as 1/2Mu_(rms)^(2) . The mean free path (lambda) is the average of distances travelled by molecules in between two successive collisions whereas collision frequency (C.F.) is expressed as number of collisions taking place in unit time. The two terms lambda and C.F. are related by : C.F = (u_("rms")/lambda) If n represents number of moles, n0 is number of molecules per unit volume, k is Boltzmann constant, R is molar gas constant, T is absolute temperature and NA is Avogadro's number then which of the following relations is wrong ?

The root mean square speed of an ideal gas is given by : u_("rms") = s

1.	The root mean square speed of an ideal gas is given by : u_("rms") = sqrt((3RT)/M)Thus we conclude that u_("rms")speed of the ideal gas molecules is proportional to square root of the temperature and inversely proportional to the square root of the molar mass. The translational kinetic energy per mole can also be given as 1/2Mu_(rms)^(2) . The mean free path (lambda) is the average of distances travelled by molecules in between two successive collisions whereas collision frequency (C.F.) is expressed as number of collisions taking place in unit time. The two terms lambda and C.F. are related by : C.F = (u_("rms")/lambda) If n represents number of moles, n0 is number of molecules per unit volume, k is Boltzmann constant, R is molar gas constant, T is absolute temperature and NA is Avogadro's number then which of the following relations is wrong ?
Answer» `P = m_0 kT` `P = n_0 RT` `P= (N KN_A T)/(V)` `n_0 = N_A xx n/V` SOLUTION :`n_0 = (n xx N_A)/(V) , K = R/(N_A), PV = NRT` `implies P = (n_0)/(N_A) xx RT = n_0 RT`. (or) `PV = nRT = nKN_A xx T` .