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The self ionization constant for pure formic acid, K = [HCOOH_(2^(+))][HCOO^(-)] has been estimated as 10^(-6) a room temperature. What percentage of formic acid molecules in pure formic acid are converted to formate ion? The density of formic acid is 1.22 g//cm^(3). |
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Answer» `0.037` weight of fromic acid in 1litre solution `= 1.22' 10^(3) g` `:' [HCOOH]= (1.22 XX 10^(3))/(46) = 26.5 M` `rArr K = [HCOOH_(2)^(+)] = 10^(-6)` `:' [HCOOH_(2)^(+)] = [HCOO^(-)]` `rArr [HCOOH]_("dissociated") = 10^(-3)` `:. (10^(-3))/(26.5) xx 100 = 0.0037` |
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