1.

The solution containing 4.0 gm of a polyvinyl chloride polymer in 1 litre of dioxane was found to have an osmotic pressure `6.0xx10^(-4)` atmosphere at 300K, the value of R used is 0.082 litre atmosphere `"mole"^(-1)K^(-1)`. The molecular mass of the polymer was found to beA. `3.0xx10^(2)`B. `1.6xx10^(-5)`C. `5.6xx10^(4)`D. `6.4xx10^(2)`

Answer» Correct Answer - B
`pi V=(w)/(m)RT`
`therefore 6xx10^(-4)xx1=(4)/(m)xx0.0821xx300 , m = 1.64xx10^(5)`


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