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| 1. |
The stabillity of +5 oxidation state dereases down the group 15 of the periodic table. Explain this observation giving appropriate reasons. |
| Answer» Solution :All the elements of GROUP 15 have five electrons in the valence shell, two in the s-subshell and three in the p- subshell. Therefore, among others, they can show positive oxidation states of +3 (due to pacticipation of only p-electrons) and +5 (due to the participation of both s- and p-electrons of the valence shell). Now N does not have d- or -f -electrons but all other elements have either d-or both d-and f-electrons in the inner shells. Since d-and f-electrons shield the s-electrons of the valence shell more effectively than the p-electrons, therefore on moving down the group tendency of s-electrons to participate in bond FORMATION decreases while that of p electrons increases. As a resulty among hevier elements of group 15, the electron pair in s-orbtial of the valence shell shows reluctance to participate in bond formation. In other words, among heavier elements, only p-electrons participate in bond formation and hence show an oxidation state of +3. This is called inert pair effect. Further, as the NUMBER of d-and f-electrons increases down the group, the inert pair efferct becomes more and more pronounced. In other words, down the group from As to Bi, the stability of +3 oxidation state increases while that of +5 oxidation state decreases. | |