1.

The standard enthalpiesof formation ofCO_(2)(g), H_(2)O(l)and glucose (s)at 25^(@)C are-400 kJ //mol, - 300 kJ//mol and-1300kJ//molrespectively.The standard enthalpy of combustion per gram of glucose at25^(@)C is

Answer»

` + 2900kJ`
` -2900kJ`
` - 16.11kJ `
`+16.11 kJ`

Solution :`C_(6)H_(12)O_(6)(s)+ 6O_(2)(g)rarr6 CO_(2)(g) +6 H_(2)O(l)`
`Delta_(r)H^(@)=Delta_(c) H^(@) = [ 6 Delta_(F)(CO_(2)) + 6 Delta_(f)H^(@) ( H_(2)O)]- [ Delta_(f) H^(@) ( C_(6)H_(12)O_(6)) + 6 Delta_(f) H^(@) ( O_(2))]`
`= 6 xx ( - 400) + 6 ( - 300) -( - 1300)`
`= -2900 kJ`
`= - ( 2900)/( 180 ) kJ //g =- 16.11 kJ //g`


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