1.

The standard Gibbs energy change at 300 K for the reaction 2A hArr B +C is 2494.2J. At a given time, the composition of the reaction mixture is [A]=(1)/(2), [B]=2 and [C]=(1)/(2). The reaction proceeds in the : [R=8.314 J//K//"mol", e=2.718]

Answer»

forward DIRECTION because `Q lt K_(e )`
REVERSE direction because `Q lt K_(e )`
forward direction because `Q GT K_(e )`
reverse direction because `Q gt K_(e )`

Solution :`DeltaG^(@)=2494.2J`
`2A hArr B+C`
`R=8.314 J//K"mol"`.
e= 2.718
`[A]=(1)/(2), [B]=2, [C]=(1)/(2)`
`Q=([B][C])/([A]^(2))=(2xx1//2)/((1)/(2))^(2)=4`
`Delta G^(@)= - 2.303 " RT LOG " K_(e)`
`2494.2J= - 2.303xx(8.314 J//K//"mol")xx(300K)log K_(e )`
`implies " log " K_(e )= -(2494.2 J)/(2.303xx8.314 J//K//"mol" xx300K)`
`implies log K_(e )= -0.4341`
`K_(e )=0.37`
`Q gt K_(e )`


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